Jika tiga atau lebih sistem berada dalam kontak termal satu sama lain dan semuanya berada dalam kesetimbangan bersama, maka dua sistem yang diambil secara terpisah berada dalam kesetimbangan satu sama lain. (kutipan dari suhu monograf T.J.Quinn)
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Misalnya, termometer klinis merkuri dalam gelas diletakkan di bawah lidah pasien dan dibiarkan mencapai kesetimbangan termal di mulut pasien – kita kemudian melihat seberapa banyak merkuri keperakan telah mengembang di batang dan membaca skala termometer untuk mengetahui suhu pasien.
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Termometer adalah alat yang mengukur suhu suatu sistem secara kuantitatif. Cara termudah untuk melakukannya adalah dengan menemukan zat yang memiliki sifat yang berubah secara teratur dengan suhunya. Cara ‘biasa’ yang paling langsung adalah yang linier:
Kemudian kita dapat menentukan suhu sistem dengan mengatakan bahwa suhu adalah kuantitas yang sama untuk kedua sistem ketika keduanya berada dalam kesetimbangan termal.
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Sifat fisik yang berbeda secara langsung bergantung pada suhu dan karena digunakan untuk pengukuran suhu, seperti, misalnya: